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  1. Friedrich-Alexander-Universität
  2. Naturwissenschaftliche Fakultät
  3. Department Chemie und Pharmazie

Department of Chemistry and Pharmacy

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  3. Bachmann group research

Bachmann group research

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Bachmann group research

Research topics

We develop chemical interface engineering methods for green energy conversion applications

Energy conversion between its light, electrical, and chemical forms always entails the transfer of charge carriers at interfaces as the crucial step. Here, “the interface is the device” — in stark contrast to the bulk amounts of materials traditionally utilized in classical energy conversion devices. Therefore, smart engineering of interfaces enables one to minimize the utilization of expensive, highly purified, rare, or toxic materials. In fact, we contend that we can even replace those materials with inexpensive, abundant, innocuous ones using a combination of interface nanostructuring (on the scale of 20 to 5000 nm) and interface functionalization by ultrathin coatings (on the scale of 0.5 to 50 nm). To achieve the level of control required, we develop chemical nanostructuring methods based mostly on atomic layer deposition (ALD) and electrochemistry. We then implement them towards devices, the functional performance of which depends on the degree of perfection achieved preparatively.

Photonic solar cells built on ordered arrays of nanospheres
Micrograph and photographs: Büttner, Döhler, Mínguez Bacho

Surface chemistry and preparative methods

Atomic-layer additive manufacturing
Sketch: Bachmann

We develop molecular surface chemistry towards novel atomic layer deposition (ALD) reactions and processes, we combine it with electrochemical techniques to create original, complex nanostructures with well-defined geometry and tunable structural parameters.

Adv. Mater. Interfaces 2023, 2300436
Small 2023, 2301774
RSC Advances 2023, 13, 4011-4018
Chem. Mater. 2022, 34, 9836-9843
Chem. Mater. 2022, 34, 9392-9401
Small Methods 2022, 2101546
Small Methods 2021, 2101296
Dalton Trans. 2021, 50, 13066
Chem. Commun. 2021, 57, 4654-4657
Adv. Mater. Interfaces 2020, 7, 2001493

Pt/Ir nanotubes
Micrograph: Licklederer

J. Mater. Chem. A 2019 ,7, 25112-25119
Nanoscale 2018, 10, 8385-8390
ACS Omega 2018, 3, 2602-2608
ECS J. Solid State Sci. Technol.2017, 6, N171-N175
Langmuir 2017, 33, 8289-8294
Nano Lett.2015, 15, 6379-6385
Rev. Sci. Instrum.
2015, 86, 073902

 

Support geometry in electrocatalysis and catalysis

ChemElectroChem 2018 issue 9 cover
ChemElectroChem cover (RSC)

We investigate systematically how increases in the specific surface area of a nanoporous electrode or porous catalyst support are reflected in the substrate turnover.

ChemCatChem 2024, e202401429
Chem. Methods 2023, e202300019
Electrochim. Acta 2022, 417, 140308
Int. J. Hydrogen Energy 2021, 46, 38972-38982
Electrochim. Acta 2021, 389, 138716
RSC Adv. 2021, 11, 17985-17992
Sust. Energy & Fuels 2021, 5, 478-485
Nanoscale Adv. 2020, 2, 1417-1426
ACS Appl. Energy Mater. 2019, 2, 2344-2349
Adv. Mater. Interfaces 2018, 1801432
ChemElectroChem 2018, 5, 1259-1264
ChemSusChem
2017, 10, 3644-3651
Nanotechnol. 2017, 28, 065405
J. Mater. Chem. A 2016, 4, 6487-6494
ChemSusChem 2016, 9, 1424-1432
ChemCatChem 2015, 7, 2455-2459
Dalton Trans. 2014, 43, 4345-4350

Photovoltaics

Ignacio's ETA solar cell cross-section
Micrograph: Minguez Bacho

We study how the efficiency of ‘extremely thin absorber’ (ETA) solar cells is affected by the thickness of the light absorbing layer and the other geometric parameters of the nanostructured semiconductor junction.

ACS Appl. Mater. Interfaces 2024, 16, 13903–13913
Nano Energy 2022, 2022, 107820
ACS Appl. Energy Mater. 2022, 5, 11977-11986
Nano Energy 2021, 89, 106373
J. Phys. Chem. C 2021, 125, 18429-18437
Small 2021, 2100487
ACS Appl. Mater. Interf. 2021, 13, 11861-11868
RSC Adv. 2020, 10, 28225-28231
ACS Appl. Energy Mater. 2019,, 2, 8747-8746
J. Mater. Chem. A
2015, 3, 5971-5981
Energy Environ. Sci.
2013, 6, 67-71

Magnetism

Research Prof. Dr. Bachmann (Image: Julien Bachmann)
Image: Bochmann

We create ordered arrays of elongated magnetic nanostructures for data storage application. By introducing structural irregularities along the axis of the structures, we aim to be able to store, read and write many bits of information per object.

J. Phys. Chem. C 2023, 127, 2387-2397
Appl. Phys. Lett.2021, 118, 172411
Phys. Rev. B
2021, 103, 054430
Phys. Rev. Lett. 2019, 123, 217201
Appl. Phys. Lett.
2018, 112, 242403
RSC Advances 2017, 7, 37627-37635
Phys. Rev. B 2015, 92, 144428

Battery materials

SnO2 nanotube electrde
Nanoscale Advances cover (RSC)

We apply our nanostructuring methods to the generation of lithium ion battery materials in which short ion transport distances within the solid and a high degree of porosity allow for fast charge and discharge, non-destructive volume changes, and high durability.

Electrochim. Acta 2021, 388, 138522
Nanoscale Adv. 2020, 2, 1417-1426
Powder Technol. 2020, 363, 218-231
Adv. Powder Technol. 2019, 30, 3127-3134

 

Friedrich Alexander University Erlangen-Nürnberg
Department of Chemistry and Pharmacy

Nikolaus-Fiebiger-Str. 10
91058 Erlangen
Germany
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