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    1. Friedrich-Alexander-Universität
    2. Naturwissenschaftliche Fakultät
    3. Department Chemie und Pharmazie

    Department of Chemistry and Pharmacy

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    Research

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      • Wet chemically synthesized nanoparticles with designed properties
      • General supraparticle formation
      • Communicating and interactive supraparticles
      • Multifunctional adsorbers and carriers
      • Multifunctional catalysts
      • Magnetic entities and magnetic particle spectroscopy (MPS)
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    Research

    Research



    In the Mandel group, we design highly functional supraparticles, i.e., particles of a few µm in size that are composed of nanoparticle (and molecular) building blocks.

    These complex entities are achieved via forced assembly of the (nano) building blocks, mainly by using the technique of spray-drying.

    We study how structure, besides (multimaterial) composition, of such supraparticles affects the interaction among the building blocks of these entities and how this leads to unique functionalities.

    We exploit these findings for designing highly innovative communicating / interactive supraparticles and multifunctional adsorber / carrier and catalyst entities.

    Many different material systems are studied in the group, but a special focus is on iron oxide nanoparticle-based magnetic systems and their characterization in particularly via magnetic particle spectroscopy (MPS), a to date rather unexplored approach that we pioneer.

    Our research fields in focus:

     

    Size, shape and composition determine the ultimate properties of nanoparticles. Chemical synthesis control enables tailoring these.­­ We synthesize and surface functionalize nanoparticles by means of bottom-up wet chemistry and subsequently use these as building blocks to assemble functional supraparticles.­ A main interest is on magnetic, luminescent, adsorber and catalyst nano building blocks.

     

     

    Selected publications: 

    Raczka T., Luthardt L., Müssig S., Kent N., Lan Q., Denneulin, T., Dunin-Borkowski R.E., Mandel K.
    Magnetically “Programming“ Cobalt-Doped Iron Oxide Nanoparticles For Localized Induction Heating: Triggering a Collective Effect of Magnetic Moment Alignment On Demand
    In: Advanced Materials (2025), just accepted

     

    Zhang K., Schötz S., Reichstein J., Groppe P., Stockinger N., Wintzheimer S., Mandel K., Libuda J., Retzer T.
    Supraparticles for naked-eye H2 indication and monitoring: improving performance by variation of the catalyst nanoparticles
    In: The Journal of Chemical Physics (2023)
    DOI: 10.1063/5.0135130

     

    Granath T., Mandel K., Löbmann P.
    The Significant Influence of the pH Value on Citrate Coordination upon Modification of Superparamagnetic Iron Oxide Nanoparticles
    In: Particle and Particle Systems Characterization (2022)
    DOI: 10.1002/ppsc.202100279

     

    Granath T., Loebmann P., Mandel K.
    Overcoming the Inhibition Effects of Citrate: Precipitation of Ferromagnetic Magnetite Nanoparticles with Tunable Morphology, Magnetic Properties and Surface Charge
    via Ferrous Citrate Oxidation
    In: Particle and Particle Systems Characterization (2021)
    DOI: 10.1002/ppsc.202100098

     

    Granath T., Loebmann P., Mandel K.
    Oxidative Precipitation as a Versatile Method to Obtain Ferromagnetic Fe3O4 Nano- and Mesocrystals Adjustable in Morphology and Magnetic Properties
    In: Particle & Particle Systems Characterization (2021)
    DOI: 10.1002/ppsc.202000307

     

    Upon droplet evaporation, using the tool spray-drying, forced assembly of nano building blocks to supraparticles is possible. Furthermore, via this method, also molecular precursors and molecules can be joined, i.e., we can also perform “chemistry in a droplet”.

    We study how structure, besides composition, of such supraparticles affects the interaction among the building blocks of these entities and how this leads to unique functionalities.

     

    Selected publications:

    Wintzheimer S., Luthardt L., Cao K.L.A., Imaz I., Maspoch D., Ogi T., Bück A., Debecker D.P., Faustini M., Mandel K.
    Multifunctional, hybrid materials design via spray-drying: much more than just drying
    In: Advanced  Materials (2023)
    DOI: 10.1002/adma.202306648

     

    Wenderoth S., Bleyer G., Endres J., Prieschl J., Vogel N., Wintzheimer S., Mandel K.
    Spray-dried photonic balls with a disordered/ordered hybrid structure for shear stress indication
    In: Small (2022)
    DOI: 10.1002/smll.202203068

     

    Wenderoth S., Eigen A., Wintzheimer S., Prieschl J., Hirsch A., Halik M., Mandel K.
    Supraparticles with a mechanically triggerable color-change-effect to equip coatings with the ability to report damage
    In: Small (2022)
    DOI: 10.1002/smll.202107513

     

    Pujales Paradela R., Granath T., Seufert M. T., Kasper T., Müller-Buschbaum K., Mandel K.
    Luminescent magnets: hybrid supraparticles of a lanthanide-based MOF and ferromagnetic iron oxide by assembly in a droplet via spray-drying
    In: Journal of Materials Chemistry C (2022)
    DOI: 10.1039/D1TC04867H

     

    Müssig S., Koch V. M., Cuadrado C. C., Bachmann J., Thommes M., Barr M. K. S., Mandel K.
    Spray-Drying and Atomic Layer Deposition: Complementary Tools toward Fully Orthogonal Control of Bulk Composition and Surface Identity of Multifunctional Supraparticles
    In: Small Methods (2021)
    DOI: 10.1002/smtd.202101296

     

    We believe that supraparticles can be turned into communicating and interactive objects – a vision that we would like to become reality. Particles are developed that carry unique IDs, are able to perceive and subsequently report environmental stimuli, and can transform their state – which includes principles of micro reactor / micro ecosystems in a particle.

     

    Selected publications:

    Deuso S., Ziegler S., Weber D., Breuer F., Haddad D., Müssig S., Flegler A., Giffin G.A., Mandel K.
    Magnetic Supraparticles as Identifiers in Single-Layer Lithium-Ion Battery Pouch Cells
    In: ChemSusChem (2024)
    DOI: 10.1002/cssc.202401142

     

    Reichstein J., Müssig S., Wintzheimer S., Mandel K.
    Communicating supraparticles to enable perceptual, information-providing matter
    In: Advanced  Materials (2023)
    DOI: 10.1002/adma.202306728

     

    Wenderoth S., Müssig S., Prieschl J., Genin E., Heuzé K., Fidler F., Haddad D., Wintzheimer S., Mandel K.
    Optically sensitive and magnetically identifiable supraparticles as indicators of surface abrasion
    In: Nano Letters (2022)
    DOI: 10.1021/acs.nanolett.1c04773

     

    Reichstein J., Schötz S., Macht M., Maisel S., Stockinger N., Cuadrado Collados C., Schubert K, Blaumeiser D., Wintzheimer S., Görling A., Thommes M., Zahn D., Libuda J., Bauer T., Mandel K.
    Supraparticles for Bare-Eye H2 Indication and Monitoring: Design, Working Principle, and Molecular Mobility
    In: Advanced Functional Materials (2022)
    DOI:10.1002/adfm.202112379

     

    Müssig S., Reichstein J., Miller F., Mandel K.
    Colorful Luminescent Magnetic Supraparticles: Expanding the Applicability, Information Capacity and Security of Micron-scaled Identification Taggants by Dual-Spectral Encoding
    In: Small (2022)
    DOI: 10.1002/smll.202107511

     

    Reichstein J., Miller F., Wintzheimer S., Mandel K.:
    Communicating Particles: Identification Taggant and Temperature Recorder in One Single Supraparticle
    In: Advanced Functional Materials (2021)
    DOI: 10.1002/adfm.202104189

     

    Joining different nano building blocks to supraparticles is particularly interesting for adsorber and carrier systems. Firstly, porous systems can be generated (via interstitial and/or templated pore formation). Secondly, besides chemical adsorber affinity / carrier design, further functionality addition is possible such as magnetic properties for separation or inductive heatability of the system.

     

    Selected publications:

    Drenkova-Tuhtan A., Inskeep C. S., Luthardt L., Deuso S., Ballweg T., Hanselmann D., Bealu Z., Meyer C., Schug B., Steinmetz H., Mandel K.
    Reusable and inductively regenerable magnetic activated carbon for removal of organic micropollutants from secondary wastewater effluents
    In: Water Research (2024)
    DOI: 10.1016/j.watres.2024.121525

     

    Schneider M., Tschoepe A., Hanselmann D., Ballweg T., Cehermann C., Franzreb M., Mandel K.
    Adsorber Particles with Magnetically-Supported Improved Electrochemical Conversion Behavior for Waste Water Treatment Processes
    In: Particle & Particle Systems Characterization (2020)
    DOI: 10.1002/ppsc.201900487

     

    Schneider M., Ballweg T., Gross L., Cellermann C., Sanchez-Sanchez A., Fierro V., Ceizard A., Mandel K.
    Magnetic Carbon Composite Particles for Dye Adsorption from Water and their Electrochemical Regeneration
    In: Particle & Particle Systems Characterization (2019)
    DOI: 10.1002/ppsc.201800537

     

    Oppmann M., Wozar M., Reichstein J., Mandel K.
    Reusable Superparamagnetic Raspberry-Like Supraparticle Adsorbers as Instant Cleaning Agents for Ultrafast Dye Removal from Water
    In: ChemNanoMat (2019)
    DOI: 10.1002/cnma.201800490

     

    Drenkova-Tuhtan A., Schneider M., Franzreb M., Meyer C., Gellermann C., Sextl G., Mandel K., Steinmetz H.
    Pilot-scale removal and recovery of dissolved phosphate from secondary wastewater effluents with reusable ZnFeZr adsorbent @ Fe3O4/SiO2 particles with magnetic harvesting
    In: Water Research (2017)
    DOI: 10.1016/j.watres.2016.11.039

     

    Supraparticles can provide an emergent, tunable porosity and precisely configurable accessibility of active catalyst sites, thus, enhanced catalytic activity and stability. Their flexible setup also permits the integration of multiple different building blocks, which allows for coupling interactions within the material, e.g., energy transfers, or the addition of further functionalities such as an inductive heatability of the systems. For the direct application of supraparticles in catalytic fixed-bed reactors, their attachment on beads, yielding ‘suprabeads’, is a strategy to increase their size regime without compromising their unique supraparticle-based functionality.

     

    Selected publications:

    Groppe P., Müller V., Will J., Zhou X., Zhang K., Moritz M.S. , Papp C., Libuda J., Retzer T., Spiecker E., Bachmann J., Mandel K., Wintzheimer S.
    Atomic Layer Deposition on Spray-dried Supraparticles to Rationally Design Catalysts with Ultralow Noble Metal Loadings
    In: Chemistry of Materials (2025)
    DOI: 10.1021/acs.chemmater.4c03429

     

    Gryn S, Kurmach M., Yaremov P., Shvets O., Alekseev S., Wintzheimer S., Mandel K.
    Design of hierarchical TS-1 zeolites using spray-drying for enhanced catalytic activity in cyclic carbonate formation
    In: Microporous and Mesoporous Materials (2025)
    DOI: 10.1016/j.micromeso.2025.113610

     

    Groppe P., Reichstein J., Carl S., Cuadrado Collados C., Niebuur B., Zhang K., Apeleo Zubiri B., Libuda J. Kraus K. Retzer T. Thommes M., Spiecker E., Wintzheimer S., Mandel K.,
    Catalyst Supraparticles: Tuning the Structure of Spray-dried Pt/SiO2 Supraparticles via Salt-based Colloidal Manipulation to Control their Catalytic Performance
    In: Small (2024)
    DOI: 10.1002/smll.202310813

     

    Zimmermann T., Madubuko N., Groppe P., Raczka T., Dünninger N., Tacardi N., Carl S., Apeleo Zubiri B., Spiecker E., Wasserscheid P., Mandel K., Haumann M., Wintzheimer S.
    Supraparticles on beads for supported catalytically active liquid metal solutions – the SCALMS suprabead concept
    In: Materials Horizons (2023)
    DOI: 10.1039/D3MH01020A

     

    Zhang K., Reichstein J., Groppe P., Schötz S., Stockinger N., Libuda J., Mandel K., Wintzheimer S., Retzer T.
    Molecular and structural insights into H2 indicator supraparticles: lowering the limit of detection by tuning incorporated catalyst nanoparticles
    In: Chemistry of Materials (2023)
    DOI: 10.1021/acs.chemmater.3c01105

    Iron oxide-based nanoparticles can be engineered to be magnetically steerable, inductively heatable or chemically reactive. Joined to entites such as supraparticles, collective magnetic interaction occurs. Besides designing these magnetic interactions, we also study them via the method of magnetic particle spectroscopy (MPS) that we pioneer and consider as a very powerful tool that provides new eyes to study processes or materials when it is dark, i.e., when one cannot use (light) optical means.

     

    Selected publications:

    Müssig S., Wolf A., Kämäräinen T., Mandel K.
    Information-providing magnetic supraparticles: particle designs to record environmental stimuli with readout by magnetic particle spectroscopy
    In: Accounts of Materials Research (2025)
    DOI: 10.1021/accountsmr.5c00027

     

    Wolf A., Heinlein M., Kent N., Müssig S., Mandel K.
    Bulk magnetic properties arise from micron-sized supraparticle interactions and can be modified on the nanoscale
    In: Small (2025)
    DOI: 10.1002/smll.202412311

     

    Wolf A., Sauer J., Hurle K., Müssig S. and Mandel K.
    Magnetic supraparticles capable of recording high temperature events
    In: Advanced Funtional Materials (2024)
    DOI: 10.1002/adfm.202316212

     

    Reichstein J., Müssig S., Bauer H., Wintzheimer S., Mandel K.
    Recording Temperature with Magnetic Supraparticles
    In: Advanced  Materials (2022)
    DOI: 10.1002/adma.202202683

     

    Müssig S., Reichstein J., Prieschl J., Wintzheimer S., Mandel K.
    A Single Magnetic Particle with Nearly Unlimited Encoding Options
    In: Small (2021)
    DOI: 10.1002/smll.202101588

     

     

     

     

     

     

    Friedrich Alexander University Erlangen-Nürnberg
    Department of Chemistry and Pharmacy

    Nikolaus-Fiebiger-Str. 10
    91058 Erlangen
    Germany
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