Research

Our research efforts are directed towards the design of novel chiral organometallic transition metal complexes, which serve as catalysts for the asymmetric synthesis of optically active organic molecules. We are also interested in developing new strategies for the activation and monetization of CO2.

 

Publications

Diarylformamides as a Safe Reservoir and Room Temperature Source of Ultra-Pure CO in the Context of a ‘Green’ rWGS Reaction

Royel Hurtado, Lisha Lou, Lukas Klerner, Iman Dindarloo Inaloo, Frank W. Heineman, Sjoerd Harder, Günter Schmid, Romano Dorta

ChemSusChem 2024, e202400308

Dalton Transactions HOT Article:
Dibenzoazepine hydrazine is a building block for N-alkene hybrid ligands: Exploratory syntheses of complexes of Cu, Fe, and Li
Alexander Grasruck, Kristina Schall, Frank W. Heinemann, Jens Langer, Alberto Herrera, Sybille Frieß, Günter Schmid, Romano Dorta

Dalton Trans., 2024, 53, 8642.

Electrical energy input efficiency limitations in CO2-to-CO electrolysis and attempts for improvement


Thomas Reichbauer, Bernhard Schmid, Kim-Marie Vetter, David Reinisch, Nemanja Martić, Christian Reller, Alexander Grasruck, Romano Dorta, Günter Schmid

Electrochem. Sci. Adv. 2023;1–16.
DOI:http://10.1002/elsa.202300024

Trapping of soluble, KCl-stabilized Cu(I) hydrides with CO2 gives crystalline formates


Alexander Grasruck,  Giorgio Parla, Lisha Lou, Jens Langer, Christian Neiß, Alberto Herrera, Sybille Frieß, Andreas Görling, Günter Schmid, Romano Dorta

Chem. Commun., 2023, 59, 13879–13882
DOI:http://10.1039/d3cc03033d

Stereochemical Stability of Planar-Chiral Benzazepine Tricyclics: Inversion Energies of P- and S‐Alkene Ligands


Jacqueline Calderón, Alberto Herrera, Frank W. Heinemann, Jens Langer, Anthony Linden, Ahmed Chelouan, Alexander Grasruck, Rafael Añez, Timothy Clark, Romano Dorta


J. Org. Chem. 2023, 88, 16144−16154
DOI:https://doi.org/10.1021/acs.joc.3c01447

Evolution of a ‘privileged’ P-alkene ligand: Added planar chirality beats BINOL axial chirality in catalytic asymmetric C–C bond formation


Luisa Leinauer, Giorgio Parla, Julian Messelberger, Alberto Herrera, Frank W. Heinemann, Jens Langer, Ilya Chuchelkin, Alexander Grasruck,  Sibylle Frieß, Ahmed Chelouan, Konstantin Gavrilov, Romano Dorta

Chem. Commun., 2023, 59, 13879–13882
DOI:https:// doi.org/10.1039/d3cc04972h

C2 and C1-Symmetric Camphopyrazole Dioxomolybdenum(VI) Complexes catalyze the Epoxidation of Cyclic Olefins
Tania Aguilera, Jesús Pastrán, Ligia Llovera, Anthony Linden, Alberto Herrera, Doménico Venuti, Giuseppe Agrifoglio, and Romano Dorta

Z. Anorg. Allg. Chem. 2023, e202300104
DOI:http://10.1002/zaac.202300104

Developing bulky P-alkene ligands: Stabilization of copper complexes with 14 valence electrons

Alexander Grasruck, Giorgio Parla, Frank W. Heineman, Jens Langer, Alberto Herrera, Sybille Frieß, Günter Schmid, Romano Dorta

New J. Chem. 2023, 47, 2307-2323
DOI: 10.1039/d2nj05222a

On the Effect of Iodide and Acid in the Metolachlor Process

Kevin Breitwieser, Romano Dorta, Dominik Munz

Organometallics  2022, 41, 3801-3808
DOI: 10.1021/acs.organomet.2c00385

Featured Article:

Ir(IV) Sulfoxide-Pincer Complexes by Three-Electron Oxidative Additions of Br2 and I2.

Unprecedented Trap-Free Reductive Elimination of I2 from a formal d5 Metal


Sibylle Frieß, Anna Benyak, Alberto Herrera, Ana M. Escalona, Frank W. Heinemann, Jens Langer, Dominik Fehn, Daniel Pividori, Alexander Grasruck, Dominik Munz, Karsten Meyer, Romano Dorta

Inorganic Chemistry  2022, 61, 3, 1236-1248
DOI: 10.1021/acs.inorgchem.1c02956

Tricyclic Sulfoxide–Alkene Hybrid Ligands for Chiral Rh(I) Complexes:

The “Matched” Diastereomer Catalyzes Asymmetric C–C Bond Formations

Alexander Nikol, Ziyun Zhang, Ahmed Chelouan, Laura Falivene, Luigi Cavallo, Alberto Herrera, Frank W. Heinemann, Ana Escalona, Sibylle Frieß, Alexander Grasruck, and Romano Dorta

Organometallics 2020, 39, 8, 1348–1359
DOI: 10.1021/acs.organomet.0c00094

Towards enantiopure macrocyclic trans-dinucleating hemilabile P-Alkene ligands: Syntheses, structures, and Chiral Pd-Complexes


Sibylle Frieß, Alberto Herrera, Anthony Linden, Frank W. Heinemann and Romano Dorta

J. Organomet. Chem. 2019, 898, 120876
DOI: 10.1016/j.jorganchem.2019.120876

Developing Chiral Dibenzazepine-Based S(O)-Alkene Hybrid Ligands for Rh(I) Complexation:

Catalysts for the Base-Free Hayashi–Miyaura Reaction

Ahmed Chelouan, Siyuan Bao, Sibylle Frieß, Alberto Herrera, Frank W. Heinemann, Ana Escalona, Alexander Grasruck, and Romano Dorta

Organometallics 2018, 37, 21, 3983-3992
DOI: 10.1021/acs.organomet.8b00591

C2-Symmetric (SO)N(SO) Sulfoxide Pincer Complexes of Mg and Pd:

Helicity Switch by Ambidentate S/O-Coordination and Isolation of a Chiral Pd-Sulfenate

Falk W. Seidel, Sibylle Frieß, Frank W. Heinemann, Ahmed Chelouan, Andreas Scheurer, Alexander Grasruck, Alberto Herrera and Romano Dorta

Organometallics 2018, 37, 7, 1160–1171
DOI: 10.1021/acs.organomet.8b00038

Developing P-Stereogenic, Planar–Chiral P-Alkene Ligands:

Monodentate, Bidentate and Double Agostic Coordination Modes on Ru(II)

Alberto Herrera, Alexander Grasruck, Frank W. Heinemann, Andreas Scheurer, Ahmed Chelouan, Sibylle Frieß, Falk Seidel and Romano Dorta

Organometallics 2017, 36, 3, 714–720
DOI: 10.1021/acs.organomet.6b00879

s-Block Metal Dibenzoazepinate Complexes: Evidence for Mg-Alkene Encapsulation

Benjamin Freitag, Holger Elsen, Jürgen Pahl, Gerd Ballmann, Alberto Herrera, Romano Dorta and Sjoerd Harder

Organometallics 2017, 26, 1860-1866
DOI: 10.1021/acs.organomet.7b00200

Chiral Amino-Phosphine and Amido-Phosphine Complexes of Ir and Mg. Catalytic Applications in Olefin Hydroamination

Bernhard Schmid, Sibylle Frieß, Alberto Herrera, Anthony Linden, Frank W. Heinemann, Harald Locke, Sjoerd Harder and Romano Dorta

Dalton Trans. 2016, 45, 12028-12040
DOI: 10.1039/c6dt01146b

 

Camphopyrazole-Based N,N- and N,P-Ligands and Chiral Complexes of Ni, Pd, and Rh: P–N Bond Activation upon Rh(I) Complexation

Alberto Herrera, Alexander Briceño, Teresa Gonzalez, Anthony Linden, Frank W. Heinemann, Giuseppe Agrifoglio, Jesús Pastrán and Romano Dorta

Tetrahedron-Asymmetry 2016, 27, 759-767
DOI: 10.1016/j.tetasy.2016.06.013

Optimized Syntheses of Optically Pure P-Alkene Ligands: Crystal Structures of a Pair of P-Stereogenic Diastereomers


Alberto Herrera, Anthony Linden, Frank W. Heinemann, René-Chris Brachvogel, Max von Delius, Romano Dorta
Synthesis 2016; 48, 1117-1121
DOI: 10.1055/s-0035-1560410

Chiral (SO)–N–(SO) Sulfoxide Pincer Complexes of Mg, Rh, and Ir:

N–H Activation and Selective Sulfoxide Reduction upon Ligand Coordination


Harald Locke, Alberto Herrera, Frank W. Heinemann, Sibylle Frieß, Bernhard Schmid and Romano Dorta

Organometallics 2015, 34, 10, 1925-1931
DOI: 10.1021/acs.organomet.5b00178

“Chiral-at-Metal” Hemilabile Nickel Complexes with a Latent d10-ML2 Configuration:

Receiving Substrates with Open Arms


Anthony Linden, Ligia Llovera, Julio Herrera, Reto Dorta, Giuseppe Agrifoglio and Romano Dorta

Organometallics 2012, 31, 6162-6171
DOI: 10.1021/om300484z

 

Hemilabile P-Alkene Ligands in Chiral Rhodium and Copper Complexes: Catalytic Asymmetric 1,4 Additions to Enones

Emma Drinkel, Alexander Briceno, Reto Dorta and Romano Dorta

Organometallics 2010, 29, 2503-2514
DOI: 10.1021/om100248u

 

Chiral Dibenzazepine-Based P-Alkene Ligands and Their Rhodium Complexes: Catalytic Asymmetric 1,4 Addition to Enones


Ronaldo Mariz, Alexander Briceno, Reto Dorta, Romano Dorta

Organometallics 2008, 27, 6605-6613
DOI: 10.1021/om800793q